685104 - Chemical product CaterFlame - Free user manual and instructions

USER MANUAL 685104 CaterFlame

according to Regulation (EC) No 1907/2006

Brennpaste

Print date: 29.11.2021

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Brennpaste

Further trade names

Ethanol Gel, fuel gel, fuel paste, brandpasta

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Using material as fuel sources, limited exposure to unburned product to be expected

1.3. Details of the supplier of the safety data sheet

Company name:	EMGA INTERNATIONAL B.V.
Street:	Groot Mijdrechtstraat 42
Place:	NL 3641 RW Mijdrecht
Telephone:	[phone]
e-mail:	[e-mail]
Internet:

1.4. Emergency telephone number:

[phone]

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Indications of danger: F - Highly flammable, Xi - Irritant

R phrases:

Highly flammable.

Irritating to eyes.

GHS classification

Hazard categories:

Flammable liquid: Flam. Liq. 2

Serious eye damage/eye irritation: Eye Irrit. 2

Hazard Statements:

Highly flammable liquid and vapour.

Causes serious eye irritation.

2.2.Label elements

Signal word:	Danger
Pictograms:	GHS02-GHS07

Hazard statements

H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting equipment.

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Brennpaste

Print date: 29.11.2021

Page 2 of 9

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

P370+P378 In case of fire: Use Water. to extinguish.

P403+P235 Store in a well-ventilated place. Keep cool.

2.3. Other hazards

This material can be ignited by heat, sparks, flames, or other sources of ignition (e.g., static electricity, pilot lights, mechanical/electrical equipment, and electronic devices such as cell phones, computers, calculators, and pagers which have not been certified as intrinsically safe).

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components

EC No	Chemical name	Quantity
CAS No	Classification
Index No	GHS classification
REACH No
200-578-6	ethanol, ethyl alcohol	70 %
64-17-5	F - Highly flammable, Xi - Irritant R11-36
603-002-00-5	Flam. Liq. 2, Eye Irrit. 2; H225 H319
213-791-2	water	30 %
7732-18-5

Full text of R and H phrases: see Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information

In all cases of doubt, or when symptoms persist, seek medical advice.

After inhalation

Provide fresh air. Remove casualty to fresh air and keep warm and at rest. In case of inhaling spray mist, consult a doctor immediately and show him packing or label.

After contact with skin

Wash with plenty of water. Take off contaminated clothing and wash it before reuse. In case of skin irritation consult a physician.

After contact with eyes

After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an ophthalmologist immediately. If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at least 5 minutes. Subsequently consult an ophthalmologist.

After ingestion

Observe risk of aspiration if vomiting occurs. Rinse mouth immediately and drink plenty of water.

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Brennpaste

Print date: 29.11.2021

Page 3 of 9

4.2. Most important symptoms and effects, both acute and delayed

No information available.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically. First Aid, decontamination, treatment of symptoms.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Water spray jet, Carbon dioxide (CO2), Foam, Extinguishing powder. Carbon dioxide (CO2). Dry extinguishing powder. alcohol resistant foam. Atomized water.

5.2. Special hazards arising from the substance or mixture

Flammable. Vapours can form explosive mixtures with air.

5.3. Advice for firefighters

In case of fire: Wear self-contained breathing apparatus.

Additional information

Use water spray jet to protect personnel and to cool endangered containers. Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Remove all sources of ignition. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Use personal protection equipment. Vapours are heavier than air and will spread at floor level. Take precautionary measures against static discharge.

6.2. Environmental precautions

Do not allow uncontrolled discharge of product into the environment. Danger of explosion

6.3. Methods and material for containment and cleaning up

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal. Spilled product must never be returned to the original container for recycling.

6.4. Reference to other sections

Safe handling: see section 7

Personal protection equipment: see section 8

Disposal: see section 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling

The formation of combustible vapours is possible at temperatures above: 18°C. Use only in well-ventilated areas. Keep away from sources of ignition. - No smoking. Flammable vapours can accumulate in head space of closed systems. Caution! Transport usually takes place at temperatures above the flash point.

Advice on protection against fire and explosion

Keep away from sources of ignition. - No smoking. Take precautionary measures against static discharge. Vapours can form explosive mixtures with air. Take precautionary measures against static discharge. Vapours may form explosive mixtures with air.

Further information on handling

Do not breathe gas/fumes/vapour/spray.

7.2. Conditions for safe storage, including any incompatibilities

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Brennpaste

Print date: 29.11.2021

Page 4 of 9

Requirements for storage rooms and vessels

Keep container tightly closed. Keep in a cool, well-ventilated place. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Advice on storage compatibility

Do not store together with: Oxidising agent. Pyrophoric or self-heating substances.

Further information on storage conditions

Suitable material for Container: Aluminium. steel. rustproof steel. Protect against: heat.

7.3. Specific end use(s)

Using material as fuel sources, limited exposure to unburned product to be expected

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

CAS No	Substance	ppm	mg/m3	fibres/ml	Category	Origin
64-17-5	Ethanol	1000	1920		TWA (8 h)	WEL
		-	-		STEL (15 min)	WEL

Additional advice on limit values

TLV-Name: Fuel Gel

TLV-TWA (mg/m³): 5

TLV-STEL (ppm): 10

8.2. Exposure controls

Occupational exposure controls

If technical exhaust or ventilation measures are not possible or insufficient, respiratory protection must be worn.

Protective and hygiene measures

Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands and face before breaks and after work and take a shower if necessary. When using do not eat or drink. Do not eat, drink, smoke or sneeze at the workplace.

Respiratory protection

In case of inadequate ventilation wear respiratory protection. If technical exhaust or ventilation measures are not possible or insufficient, respiratory protection must be worn. Suitable respiratory protective equipment: Self-contained open circuit breathing apparatus (compressed air breathing apparatus) (EN 137).

Hand protection

When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances.

Suitable material: NBR (Nitrile rubber).

Required properties: antistatic. liquid-tight.

Eye protection

Suitable eye protection: goggles.

Skin protection

Flame-retardant protective clothing. Wear anti-static footwear and clothing

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Brennpaste

Print date: 29.11.2021

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state:	Paste
Colour:	colourless
Odour:	like: Alcohol
		Test method
pH-Value:		not determined
Changes in the physical state
Melting point:		not determined
Initial boiling point and boiling range:		85 °C
Flash point:		18 °C
Flammability
Solid:		not applicable
Gas:		not applicable
Lower explosion limits:		0,56 vol. %
Upper explosion limits:		8 vol. %
Auto-ignition temperature
Solid:		425°C
Gas:		not applicable
Oxidizing properties
Not oxidizing.
Vapour pressure:		not determined
Vapour pressure:(at 50 °C)		0,6 hPa
Density:		0,803 g/cm ^3
Water solubility:(at 20 °C)		0 g/L
Solubility in other solvents:	not determined
Partition coefficient:	not determined
Viscosity / kinematic:(at 25 °C)		3,97 mm ^2 /s
Vapour density:		not determined
Evaporation rate:		not determined
Solvent content:		562,1 g/l
9.2. Other information
Solid content:		not determined

SECTION 10: Stability and reactivity

10.1. Reactivity

Flammable, Ignition hazard.

10.2. Chemical stability

The product is stable under storage at normal ambient temperatures.

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Brennpaste

Print date: 29.11.2021

Page 6 of 9

10.3. Possibility of hazardous reactions

No known hazardous reactions.

10.4. Conditions to avoid

Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Vapours can form explosive mixtures with air.

10.5. Incompatible materials

No information available.

10.6. Hazardous decomposition products

Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity

Acute toxicity, oral

LD50: Rat >2000 mg/kg

Acute toxicity, dermal

LD50: Rat. >2000 mg/kg

Acute toxicity, inhalant

LC50: Rat. > 5mg/l Exposure time: 4h

CAS No	Chemical name
	Exposure routes	Method Dose	Species	h
64-17-5	ethanol, ethyl alcohol
	Acute oral toxicity	LD50 6200 mg/kg	Rat
	Acute inhalation toxicity	LC50 95,6 mg/l	Rat	4

Irritation and corrosivity

Irritant effect on the eye: Irritant.

After skin contact: mild irritant.

Sensitising effects

After skin contact: no danger of sensitization.

Additional information on tests

This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP].

Further information

There are no data available on the preparation/mixture itself. Data apply to the main component.

SECTION 12: Ecological information

12.1. Toxicity

Acute fish toxicity LC50: >100mg/l

Acute Daphnia toxicity EC50: >100mg/l

Algae toxicity EC50: 100mg/l

Bacterial toxicity: EC50: 100mg/l

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Brennpaste

Print date: 29.11.2021

Page 7 of 9

CAS No	Chemical name
	Aquatic toxicity	Method Dose	Species	h
64-17-5	ethanol, ethyl alcohol
	Acute crustacea toxicity	EC50 9268 - 14221 mg/l	Daphnia magna	48 h

12.2. Persistence and degradability

The product has not been tested. Product is partially biodegradable. Significant residues remain. Mechanical separation in a suitable sewage plant is possible.

12.3. Bioaccumulative potential

The product has not been tested.

Partition coefficient n-octanol/water

CAS No	Chemical name	Log Pow
64-17-5	ethanol, ethyl alcohol	-0,31

12.4. Mobility in soil

The product has not been tested.

12.5. Results of PBT and vPvB assessment

The product has not been tested.

12.6. Other adverse effects

No information available.

Further information

No special environmental measures are necessary.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal

Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation.

Waste disposal number of waste from residues/unused products

130703 OIL WASTES AND WASTES OF LIQUID FUELS (except edible oils, and those in chapters 05, 12 and 19); wastes of liquid fuels; other fuels (including mixtures) Classified as hazardous waste.

Waste disposal number of contaminated packaging

150110 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); packaging containing residues of or contaminated by dangerous substances Classified as hazardous waste.

Contaminated packaging

Wash with plenty of water. Completely emptied packages can be recycled.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: 1325

14.2. UN proper shipping name: FLAMMABLE SOLID, ORGANIC, N.O.S.; FUEL GEL

14.3. Transport hazard class(es): 4.1

14.4. Packing group: II

Hazard label: 4.1

Classification code: F1

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Brennpaste

Print date: 29.11.2021

Page 8 of 9

Limited quantity: LQ8

Hazard No: 40

Tunnel restriction code: E

Other applicable information (land transport)

Special provisions: 274

Limit Quantity: E2

Transport category: 2

Inland waterways transport (ADN)

14.1. UN number: 1325

14.2. UN proper shipping name: FLAMMABLE SOLID, ORGANIC, N.O.S.; FUEL GEL

14.3. Transport hazard class(es): 4.1

14.4. Packing group:

Hazard label: 4.1

Classification code: F1

Limited quantity: LQ8

Other applicable information (inland waterways transport)

Special provisions: 274

Limit Quantity: E2

Marine transport (IMDG)

14.1. UN number: 1325

14.2. UN proper shipping name: FLAMMABLE SOLID, ORGANIC, N.O.S.

14.3. Transport hazard class(es): 4.1

14.4. Packing group: II

Hazard label: 4.1

Marine pollutant:

Limited quantity: 1 kg

EmS: F-A, S-G

Other applicable information (marine transport)

Special provisions: 274, 915, 944

Limit Quantity: E2

Air transport (ICAO)

UN/ID number: UN1325

14.2. UN proper shipping name: FLAMMABLE SOLID, ORGANIC, N.O.S.

14.3. Transport hazard class(es): 4.1

14.4. Packing group:

Hazard label: 4.1

Special Provisions: A3

Limited quantity Passenger: 5 kg

IATA-packing instructions - Passenger: 445

IATA-max. quantity - Passenger: 15 kg

IATA-packing instructions - Cargo: 448

IATA-max. quantity - Cargo: 50 kg

Other applicable information (air transport)

Limit Quantity: E2

Passenger-LQ: Y415

Special provisions: A3

Passenger-LQ: Y441

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Brennpaste

Print date: 29.11.2021

Page 9 of 9

14.6. Special precautions for user

Warning: Flammable solids.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

1999/13/EC (VOC): 70 % (562,1 g/l)

National regulatory information

Employment restrictions: Observe employment restrictions for young people. Observe employment restrictions for child bearing mothers and nursing.

Water contaminating class (D): 1 - slightly water contaminating

Additional information

100; 110

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Abbreviations and acronyms

(European Agreement concerning the International Carriage of Dangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

GHS: Globally Harmonized System of Classification and Labelling of Chemicals

EINECS: European Inventory of Existing Commercial Chemical Substances

ELINCS: European List of Notified Chemical Substances

CAS: Chemical Abstracts Service

LC50: Lethal concentration, 50%

LD50: Lethal dose, 50%

Full text of R phrases referred to under Sections 2 and 3

11 Highly flammable.

36 Irritating to eyes.

Full text of H statements referred to under Sections 2 and 3

H225 Highly flammable liquid and vapour.

H319 Causes serious eye irritation.

Further Information

The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)